| 17/08/2019 | 17:00 | RC Celta de Vigo | 1 | 3 | Real Madrid CF |
| 24/08/2019 | 19:00 | Real Madrid CF | 1 | 1 | Real Valladolid CF |
| 01/09/2019 | 21:00 | Villarreal CF | 2 | 2 | Real Madrid CF |
| 14/09/2019 | 13:00 | Real Madrid CF | 3 | 2 | Levante UD |
| 18/09/2019 | 21:00 | Paris Saint-Germain FC | 3 | 0 | Real Madrid CF |
| 22/09/2019 | 21:00 | Sevilla FC | 0 | 1 | Real Madrid CF |
| 25/09/2019 | 21:00 | Real Madrid CF | 2 | 0 | CA Osasuna |
| 28/09/2019 | 21:00 | Club Atlético de Madrid | 0 | 0 | Real Madrid CF |
| 01/10/2019 | 18:55 | Real Madrid CF | 2 | 2 | Club Brugge KV |
| 05/10/2019 | 16:00 | Real Madrid CF | 4 | 2 | Granada CF |
| 19/10/2019 | 21:00 | RCD Mallorca | 1 | 0 | Real Madrid CF |
| 22/10/2019 | 21:00 | Galatasaray SK | 0 | 1 | Real Madrid CF |
| 30/10/2019 | 22:15 | Real Madrid CF | 5 | 0 | CD Leganés |
| 02/11/2019 | 22:00 | Real Madrid CF | 0 | 0 | Real Betis Balompié |
| 06/11/2019 | 22:00 | Real Madrid CF | 6 | 0 | Galatasaray SK |
| 09/11/2019 | 19:30 | SD Eibar | 0 | 4 | Real Madrid CF |
| 23/11/2019 | 22:00 | Real Madrid CF | 3 | 1 | Real Sociedad de Fútbol |
| 26/11/2019 | 22:00 | Real Madrid CF | 2 | 2 | Paris Saint-Germain FC |
| 30/11/2019 | 14:00 | Deportivo Alavés | 1 | 2 | Real Madrid CF |
| 07/12/2019 | 14:00 | Real Madrid CF | 2 | 0 | RCD Espanyol de Barcelona |
| 11/12/2019 | 22:00 | Club Brugge KV | 1 | 3 | Real Madrid CF |
| 15/12/2019 | 22:00 | Valencia CF | 1 | 1 | Real Madrid CF |
| 18/12/2019 | 21:00 | FC Barcelona | 0 | 0 | Real Madrid CF |
| 22/12/2019 | 22:00 | Real Madrid CF | 0 | 0 | Athletic Club |
| 04/01/2020 | 17:00 | Getafe CF | 0 | 3 | Real Madrid CF |
| 18/01/2020 | 17:00 | Real Madrid CF | 2 | 1 | Sevilla FC |
| 26/01/2020 | 22:00 | Real Valladolid CF | Real Madrid CF | ||
| 01/02/2020 | 17:00 | Real Madrid CF | Club Atlético de Madrid | ||
| 09/02/2020 | 17:00 | CA Osasuna | Real Madrid CF | ||
| 16/02/2020 | 02:00 | Real Madrid CF | RC Celta de Vigo | ||
| 26/02/2020 | 22:00 | Real Madrid CF | Manchester City FC | ||
| 01/03/2020 | 02:00 | Real Madrid CF | FC Barcelona | ||
| 08/03/2020 | 02:00 | Real Betis Balompié | Real Madrid CF | ||
| 15/03/2020 | 02:00 | Real Madrid CF | SD Eibar | ||
| 17/03/2020 | 22:00 | Manchester City FC | Real Madrid CF | ||
| 22/03/2020 | 02:00 | Real Madrid CF | Valencia CF | ||
| 23/03/2020 | 02:00 | Levante UD | Real Madrid CF | ||
| 05/04/2020 | 02:00 | Real Sociedad de Fútbol | Real Madrid CF | ||
| 12/04/2020 | 02:00 | Real Madrid CF | RCD Mallorca | ||
| 22/04/2020 | 02:00 | RCD Espanyol de Barcelona | Real Madrid CF | ||
| 26/04/2020 | 02:00 | Real Madrid CF | Getafe CF | ||
| 03/05/2020 | 02:00 | Athletic Club | Real Madrid CF | ||
| 10/05/2020 | 02:00 | Real Madrid CF | Deportivo Alavés | ||
| 13/05/2020 | 02:00 | Granada CF | Real Madrid CF | ||
| 17/05/2020 | 02:00 | Real Madrid CF | Villarreal CF | ||
| 24/05/2020 | 02:00 | CD Leganés | Real Madrid CF |